From Biomass-Derived Furans to Aromatics with Ethanol over Zeolite
I.F. Teixeira, B.T.W. Lo, P. Kostetskyy, M. Stamatakis, L. Ye, C.C. Tang, G. Mpourmpakis, S. C.E.Tsang |
Ethylene produced in situ from ethanol dehydration over zeolite is used for the catalytic conversion of biomass-derived furans into aromatic compounds by Diels–Alder cycloaddition. In their Communication G. Mpourmpakis, S. C. E. Tsang et al. describe a rapid and renewable one-pot synthesis of aromatic compounds using liquid ethanol as a source of dienophile instead of pressurized ethylene gas. Full paper can be found in DOI: 10.1002/anie.201607477
Angew. Chem. Int. Ed. 42/2016, p.13349, DOI: 10.1002/anie.201607477